Studies in the chemistry of bridged ring systems. by Lindsay Kilmurry

Cover of: Studies in the chemistry of bridged ring systems. | Lindsay Kilmurry

Published in Toronto .

Written in English

Read online

Subjects:

  • Chemical reactions,
  • Ketones,
  • Photochemistry

Edition Notes

Book details

ContributionsToronto, Ont. University.
Classifications
LC ClassificationsLE3 T525 MA 1963 K55
The Physical Object
Pagination65 leaves.
Number of Pages65
ID Numbers
Open LibraryOL14745050M

Download Studies in the chemistry of bridged ring systems.

Read the latest chapters of Studies in Inorganic Chemistry atElsevier’s leading platform of peer-reviewed scholarly literature. The Chemistry of Inorganic Ring Systems (ISSN) - Kindle edition by R. Steudel. Download it once and read it on your Kindle device, PC, phones or tablets.

Use features like bookmarks, note taking and highlighting while reading The Chemistry of Inorganic Ring Systems (ISSN). The book is organized by element, moving from left to right in the main groups of the Periodic Table, followed by one chapter each on bonding and nomenclature of ring molecules.

The list of contributors comprises distinguished scientists from 8 Edition: 1. Further Studies of Intramolecular Michael Reactions of Nitrosoalkenes for Construction of Functionalized Bridged Ring Systems Praveen Kumar, Puhui Li, Ilia Korboukh, Tony L. Wang, Hemant Yennawar, and Steven M.

Weinreb *. Synthesis of fused and bridged ring systems James Nicolas Ong Sy Iowa State University Follow this and additional works at: Part of theOrganic Chemistry Commons This Dissertation is brought to you for free and open access by the Iowa State University Capstones, Theses and Dissertations at Iowa State University.

A wide variety of stabilized carbanions have been found to participate as nucleophiles in intramolecular Michael-type conjugate additions to in situ generated nitrosoalkenes to form bridged carbocyclic systems. The vinylnitroso platforms for these cyclizations have been prepared via two key steps involving ring-closing metathesis of vinyl chlorides and regioselective conversion of vinyl Cited by:   In conclusion, we have demonstrated that intramolecular conjugate additions of carbon nucleophiles to in situ-generated vinylnitroso compounds provides a novel approach to a wide array of highly functionalized bridged and fused ring systems.

Work is currently underway on extending this methodology to formation of other types of ring by: Spiro rings are those that share only a single atom. Like bridged compounds, a prefix, bracket, and suffix term are used to name spiro rings.

The prefix term includes the term “spiro”. If there is more than one spiro atom in a compound, dispiro, trispiro, etc.

are used to indicate the number of such junctions. Multi-Parent Systems. FR Three Components ortho- and peri-Fused Together. FR Bridged Fused Ring Systems Studies in the chemistry of bridged ring systems.

book & FR, FR, FR to FR) FR Indicated Hydrogen. References. Appendix 1. Hydrocarbon parent components in order of decreasing seniority. Appendix 2.

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Further Studies of Intramolecular Michael Reactions of Nitrosoalkenes for Construction of Functionalized Bridged Ring Systems Article in The Journal of Organic Chemistry 76(7) February.

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Bicyclic Systems - Saturated alicyclic hydrocarbon systems consisting of two rings only, having two or more atoms in common, take the name of an open chain hydrocarbon containing the same total number of carbon atoms preceded by the prefix "bicyclo-".

In bridged bicyclic compounds, the two rings share three or more atoms, separating the two bridgehead atoms by a bridge containing at least one atom. For example, norbornane, also known as bicyclo[]heptane, can be viewed as a pair of cyclopentane rings each sharing three of their five carbon atoms.

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- Cyclic hydrocarbon systems consisting of three or more rings may be named in accordance with the principles stated in Rule A The appropriate prefix "tricyclo-", "tetracyclo-", etc., is substituted for "bicyclo-" before the name of the open-chain hydrocarbon.

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The two carbon atoms shared by the three rings are called bridgehead carbon atoms. A bond or a chain of bonds connecting the bridgehead carbon atoms is called a bridge.

eg. 1: Decalin. eg. 2: bicyclo[]heptane.

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